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{"id":348364,"date":"2021-05-25T20:28:44","date_gmt":"2021-05-26T00:28:44","guid":{"rendered":"https:\/\/ordinary-times.com\/?p=348364"},"modified":"2021-05-26T07:50:57","modified_gmt":"2021-05-26T11:50:57","slug":"tech-tuesday-re-thinking-recycling","status":"publish","type":"post","link":"https:\/\/ordinary-times.com\/2021\/05\/25\/tech-tuesday-re-thinking-recycling\/","title":{"rendered":"Tech Tuesday: Re-Thinking Recycling"},"content":{"rendered":"

I’ve talked about recycling before, and the various problems with how we currently do it, and the limitations of the materials, etc.; but let’s review:<\/p>\n

    \n
  1. Paper<\/strong>: From virgin pulp until it’s done, we can recycle paper ~7 times, if we are lucky, and by the end, all we can really do with it is make paper egg cartons and drink trays<\/span>1<\/sup><\/a><\/span>.<\/li>\n
  2. Plastic<\/strong>: Plastic gets 2-3 turns through the system before it’s pointless to try again, and that is assuming we can identify and separate the various types.<\/li>\n
  3. Ceramics<\/strong>: These don’t really recycle.\u00a0 Well, aside from glass, which isn’t really a ceramic, but some folks think it is.\u00a0 That isn’t to say they can’t be re-used<\/span>2<\/sup><\/a><\/span>, but we generally can’t break ceramics down and turn them into new ceramics.<\/li>\n
  4. Textiles<\/strong>: Plastic fibers have the same issue as plastics.\u00a0 Natural fibers can be re-used<\/span>3<\/sup><\/a><\/span>, but we can’t really un-weave a bed sheet and spin it up as a new spool of thread.\u00a0 At least, no one bothers to that I am aware of.<\/li>\n
  5. Metals<\/strong>: These can be recycled indefinitely.\u00a0 Seriously, melt it down and it’s good as new.\u00a0 The crystalline structure just reforms.\u00a0 About the only tricky part is making sure we know what alloy we are adding to the mix so we get the alloy we want out of the furnace.<\/li>\n<\/ol>\n

    So aside from metals (and obviously organic stuff that can be composted), it doesn’t appear that we have a lot of recycling we can actually do<\/span>4<\/sup><\/a><\/span>.<\/p>\n

    Except, that’s not entirely true.<\/p>\n

    Paper is biodegradable.\u00a0 Burn it, pulp it into a slurry, compost it.\u00a0 Mother Nature will return it to the food chain.\u00a0 Think of it as full circle recycling.\u00a0 The paper comes from plants, and after composting it, it is returned to the plants.\u00a0 Same goes for natural textiles.\u00a0 So once we hit that 7th use, just send it back to the biosphere.<\/p>\n

    But what about plastics<\/a>?<\/p>\n

    All plastics start out as a hydrocarbon, and then we chemically tease certain refined hydrocarbons into polymers through a catalytic process called polymerization.\u00a0 If the hydrocarbon of choice is petroleum, that process looks like this<\/a>.\u00a0 One of the most common plastics in use today is polyethylene, which is a fancy word for two hydrogen atoms attached to one carbon atom and the carbon atoms are chained together with other CH2 molecules.\u00a0 That’s it, carbon and hydrogen (the definition of a hydrocarbon).<\/p>\n

    If the plastic is a bio-plastic or bio-polymer, one whose feedstock is cellulose or some other carbohydrate source (there’s that carbon – hydrogen combo again), the process is similar, but involves different catalysts, or employs bacteria, and the end results can be a bit different.<\/p>\n

    It’s important to keep in mind that not all bio-plastic is bio-degradable or compostable, so the feedstock does not make a specific plastic green.\u00a0 We could be making all of our plastic from agricultural by-products and still have the same problem we do today.<\/p>\n

    The key is those chains of molecules.\u00a0 They can be hard to break.\u00a0 Which isn’t a bad thing, since we do need materials that are lightweight and durable.\u00a0 But not every use of plastic needs to last decades.\u00a0 Food and drink containers, for example, or plastic bags, or other single use plastic products (Straws! Think of the sea turtles!).\u00a0 Hell, even cheap kids toys (you know, the kinds or toys you get from Happy Meals that your kids will forget about a week after they get them) doesn’t need to be capable of being an heirloom, not every toy is a Lego.<\/p>\n

    We can design the chains to break.\u00a0 They can be designed to break down in the presence of light, or water, or by bacteria.\u00a0 Often, those breaks just result in plastic particles that we hear about getting into our food and water supplies, basically just smaller and smaller chains of molecules.\u00a0 But if the plastic is designed to be truly bio-degradable, then it is converted to other hydrocarbons or atmospheric gases.\u00a0 Those gases, by the way, are usually carbon dioxide and methane (CH4), which are not desirable gases to release back into the atmosphere<\/span>5<\/sup><\/a><\/span>.\u00a0 And, of course, if the chains are designed to break, the plastic will degrade over time, possibly very quickly, and we may want that plastic to hang around for a while before it’s used.\u00a0 Drink bottles and plastic bags may sit for years unused, so we’d want to be able to trigger things to degrade, which is tricky, which is another way to say, expensive.<\/p>\n

    So if plastics have a limited recycle life, what do we do?<\/p>\n

    Turns out, we can do something similar<\/a> to what nature does with paper.\u00a0\u00a0\u00a0 We can pretty much run the polymerization process backwards, de-polymerization, and get the feedstock petroleum back.\u00a0 Then we can take that and run it through polymerization again to get virgin plastic once more.\u00a0 De-poly is not new, we’ve known how to do it since probably shortly after we figured out how to do polymerization.\u00a0 It’s just that it’s getting some fresh attention.\u00a0 It’s very important to note that de-polymerization doesn’t care much what kind of plastic it’s working with.\u00a0 You know the little recycling number on your yogurt cup?\u00a0 That number matters for simple recycling, but not so much to de-polymerization.\u00a0 We can even toss the various plastic foams (foam packing and insulation) in the mix.<\/p>\n

    Of course, de-polymerization takes heat, and pressure, and quite a bit of it.\u00a0 Not an outrageous amount, but a lot more than you need to simply melt plastic down and recycle it into something new.\u00a0 The required energy input strikes some people as a bad way to approach the problem, which I see as the perfect being the enemy of the good.\u00a0 We use massive amounts of energy to recycle metals, and de-polymerization happens at much lower temperatures.\u00a0 The trick is that unlike metal smelting, the de-poly process needs tight control, in that it has to all heat up at the same time, so you can’t just warm up a vat at the bottom.\u00a0 It’s not an insurmountable problem, just one that is tricky to scale (see, I used ‘tricky’ again, so you know what that means).<\/p>\n

    But it does fully break the polymer chains and reforms the base hydrocarbons.<\/p>\n

    Of course, those base hydrocarbons can also be reformed into fuels, which also irritates people who want the whole world to run on electrons harvested only from free-range, organic photo-voltaics and magnetic coils.\u00a0 For reasons…<\/p>\n

    Ideally, we’d all abandon single use plastics for compostables or paper, but that’s not going to happen.\u00a0 Plastics are here to stay, they are just too useful and convenient in a number of ways.\u00a0 And let’s all be honest, the current scheme of plastic recycling winds up with more plastic in landfills, or blowing on the wind, or in the water, than it does recycled into new stuff.\u00a0 Here we have a system that, if scaled up, can take all the plastic in your recycle bin, regardless of type, or common contamination, and fully recycle it.\u00a0 Less plastic in landfills, and, potentially, less petroleum extracted from the ground.<\/p>\n

    And I’m not being naive regarding the energy inputs or that the invisible hand of the market will make it all work in the way desired.\u00a0 It’s still too easy, relatively, to just pump more oil out of the ground.\u00a0 And still too easy to just toss plastic into a landfill.\u00a0 Such a system will probably require a subsidy or other regulatory approach to get it going.\u00a0 But we can’t keep pretending that we are recycling plastic, and unless there is a breakthrough in making plastics that can fully bio-degrade into harmless molecules on command, this is the best approach for recycling plastic.<\/p>\n


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    So aside from metals (and organic stuff that can be composted), it doesn’t appear that we have a lot of recycling we can actually do<\/p>\n","protected":false},"author":278,"featured_media":348480,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_jetpack_memberships_contains_paid_content":false,"footnotes":"","_wpscppro_custom_social_share_image":0,"_facebook_share_type":"","_twitter_share_type":"","_linkedin_share_type":"","_pinterest_share_type":"","_linkedin_share_type_page":"","_instagram_share_type":"","_medium_share_type":"","_threads_share_type":"","_selected_social_profile":[]},"categories":[30052,11877],"tags":[30584],"class_list":["post-348364","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-feature","category-techday","tag-recycling"],"yoast_head":"\nTech Tuesday: Re-Thinking Recycling - Ordinary Times<\/title>\n<meta name=\"description\" content=\"So aside from metals (and organic stuff that can be composted), it doesn't appear that we have a lot of recycling we can actually do\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/ordinary-times.com\/2021\/05\/25\/tech-tuesday-re-thinking-recycling\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Tech Tuesday: Re-Thinking Recycling - 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